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Can I read Adiabatic and Nonadiabatic Proton Transfer Rate Constants in Solution on EtoBox?
Adiabatic and Nonadiabatic Proton Transfer Rate Constants in Solution by Philip M. Kiefer; James T. Hynes is a Materials Science article available to read on EtoBox.
What is Adiabatic and Nonadiabatic Proton Transfer Rate Constants in Solution about?
Here we briefly review some nontraditional theoretical views developed in this group on acid -base proton transfer (PT) reactions AH : : : B!A À : : : HB + in solution, whose key ingredients are inclusion of the quantum character of the proton motion, the identification of a solvent coordinate as the reaction coordinate, and attention to the AB hydrogen bond in the reacting pair. The reaction rate constant is discussed in two separate quantum regimes, which we term 'adiabatic' and 'nonadiabatic', with attention given to consequences for free energy relations (FER) and kinetic isotope effects (KIEs).
Who reads Adiabatic and Nonadiabatic Proton Transfer Rate Constants in Solution?
It is typically read by researchers, students, and practitioners in Materials Science.
- Author
- Philip M. Kiefer; James T. Hynes
- Publisher
- Elsevier Science; Elsevier ; Elsevier BV (ISSN 0167-2738)
- Published
- 2004
- Language
- EN
- Field
- Materials Science (Physical Sciences)