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Can I read Structure and Bonding in Cyclic Thiolate Complexes of Copper, Silver and Gold on EtoBox?
Structure and Bonding in Cyclic Thiolate Complexes of Copper, Silver and Gold by James A.S. Howell is a Chemistry article available to read on EtoBox.
What is Structure and Bonding in Cyclic Thiolate Complexes of Copper, Silver and Gold about?
The structures of M n (SMe) n rings (M = Cu, Ag, Au; n = 2-6) and some of their PH 3 and 1,4-diaza-1,3-butadiene complexes have been calculated using DFT methods. The geometries of the calculated structures are in good agreement with representative complexes retrieved from the Cambridge Crystallographic Data Base. Though p Cu-S and M-M orbital interactions can be identified, the net bonding interaction within the ring involves r Cu-S orbital overlap. In many cases, the observed and calculated structures bear a similarity to those of appropriate members of the C n H 2n series (n = 2-8).
Who reads Structure and Bonding in Cyclic Thiolate Complexes of Copper, Silver and Gold?
It is typically read by researchers, students, and practitioners in Chemistry.
- Author
- James A.S. Howell
- Publisher
- Elsevier Science; Elsevier ; Elsevier Ltd.; Elsevier BV (ISSN 0277-5387)
- Published
- 2006
- Language
- EN
- Field
- Chemistry (Physical Sciences)