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Real-time Fourier transform IR (FTIR) spectroscopy in organometallic chemistry: mechanistic aspects of the fac to mer photoisomerization of fac-[Mn(Br)(CO)3(R-DAB)] by Cornelis J. Kleverlaan; František Hartl; Derk J. Stufkens is a Materials Science article available to read on EtoBox.

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Real-time Fourier transform IR (RT/FHR) spectroscopy was used to study the photoisomerization offac-[Mn(Br ] could be detected at room temperature for L-MeCN and identified at 273 K as a cis--cis isomer for L-P(OMe)3. RT/ FTIR spectroscopy was also used to determine the thermodynamic parameters Ea, A/-P: and A £\* of the thermal backreaction of this mer product to the parent fac isomer• For slow reactions, GC/FTIR software was used to provide a real4ime screen display of the IR spectral changes. For fast reactions ( 10-~-1 s), the high speed collect (HSC) kinetic software was used to collect 12 spectra s-~ at 2 cm-~ resolution, recording one spectrum per scan.

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Author

Cornelis J. Kleverlaan; František Hartl; Derk J. Stufkens

Publisher

Elsevier Science; Elsevier ; Elsevier BV (ISSN 1010-6030)

Published

1997

Language

EN

Field

Materials Science (Physical Sciences)