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Can I read Induktive und sterische Effekte bei der BECKMANN-CHAPMAN-Umlagerung von Alkyl-ketoxim-pikryläthern on EtoBox?
Induktive und sterische Effekte bei der BECKMANN-CHAPMAN-Umlagerung von Alkyl-ketoxim-pikryläthern by H. P. Fischer; F. Funk-Kretschmar is a Chemistry article available to read on EtoBox.
What is Induktive und sterische Effekte bei der BECKMANN-CHAPMAN-Umlagerung von Alkyl-ketoxim-pikryläthern about?
Szwnnzary. The rates of thc RECKMANN-CHAPMAN rearrangement of thc ketoximpicryl-ethers la-lk in 1,4-dichlorobutane are correlated with paramcters describing the bulk of the substituted groups R and R'. From regression analyses it is concluded that thc relative ratc constants arc inainly controlled by stcric contributions in t h e ground state, such as gerninal interactions of R with R' and vicinal interactions of R' with W X , and less by inductive effects. ## Conformational equilibria between ( Z ) -and (E)-isomers of N-alkyl -N-picryl-amids have bcen stndicd by IL'MR. in several solvents. Relative Reaktionsgeschwindigkeiten von REcKMANN-Umlagerungen [l] [2] ~~i $ i , V J : ' ~I C . \ ~. k i I > I l < : , \ :\Cl.\ ~ YCJI. 52, 1'XX. 4 (1%')) . Nl-.
Who reads Induktive und sterische Effekte bei der BECKMANN-CHAPMAN-Umlagerung von Alkyl-ketoxim-pikryläthern?
It is typically read by researchers, students, and practitioners in Chemistry.
- Author
- H. P. Fischer; F. Funk-Kretschmar
- Publisher
- John Wiley and Sons; Wiley (John Wiley & Sons); Wiley-Blackwell; Wiley (ISSN 0018-019X)
- Published
- 1969
- Language
- EN
- Field
- Chemistry (Physical Sciences)