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Highly Selective and Sensitive Tin(II) Membrane Electrode Based on a New Synthesized Schiff's Base by Morteza Hosseini; Hayedeh Bagheri Sadeghi; Mohammad Rahimi; Masoud Salavati‐Niasari; Shiva Dehghan Abkenar; Kamal Alizadeh; Mohammad Reza Ganjali is a Engineering article available to read on EtoBox.
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## Abstract Studies on complex formation of tris(3‐(2‐hydroxybenzophenone)propyl)amine (THPA) with a number of metal ions in acetonitrile solution revealed the occurrence of a selective 1 : 1 complexation of the proposed ligand with Sn^2+^ ion. Consequently, THPA was used as a suitable neutral ionophore for the preparation of a polymeric membrane‐selective electrode. The electrode exhibits a Nernstian behavior with a slope of 29.4±0.3 mV per decade and a detection limit of 2.0×10^−7^ M. It also showed a good selectivity for Sn^2+^ ions in comparison with some of group A and B metal ions over a wide concentration range of 5.0×10^−7^–1.0×10^−1^ M. Improved selectivity was achieved compared to the best selectivity recently reported by other authors for tin(II). The electrode was successfully applied to the determination of Sn^2+^ ion in waste water and various canned products.
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- Author
- Morteza Hosseini; Hayedeh Bagheri Sadeghi; Mohammad Rahimi; Masoud Salavati‐Niasari; Shiva Dehghan Abkenar; Kamal Alizadeh; Mohammad Reza Ganjali
- Publisher
- John Wiley and Sons; Wiley (John Wiley & Sons); Wiley - V C H Verlag GmbbH & Co.; Wiley (ISSN 1040-0397)
- Published
- 2009
- Language
- EN
- Field
- Engineering (Physical Sciences)