Can I read Radical-Initiated Hydrosilylation-Cyclization Reactions of Bis(vinyldimethylsilyl) Compounds, CH~2~=CH(CH~3~)~2~SiXSi(CH~3~)~2~CH=CH~2~ (X = O, CH~2~, NH, NCH~3~, NSi on EtoBox?

Radical-Initiated Hydrosilylation-Cyclization Reactions of Bis(vinyldimethylsilyl) Compounds, CH~2~=CH(CH~3~)~2~SiXSi(CH~3~)~2~CH=CH~2~ (X = O, CH~2~, NH, NCH~3~, NSi by Dietmar Seyferth; Holger Friedrich; Shane W. Krska is a Chemistry article available to read on EtoBox.

What is Radical-Initiated Hydrosilylation-Cyclization Reactions of Bis(vinyldimethylsilyl) Compounds, CH~2~=CH(CH~3~)~2~SiXSi(CH~3~)~2~CH=CH~2~ (X = O, CH~2~, NH, NCH~3~, NSi about?

The di-tert-butyl peroxide-initiated reactions of triethyl- and tri-n-propylsilane with bis-(vinyldim ethylsilyl) compounds, CH~2~=CH(CH~3~)~2~SiXSi(CH~3~)~2~CH=CH~2~(X-O,CH~2~, NH,NCH~3~ and NSiMe~3~) resulted in hydrosilylation-cyclization to give mixtures of trialkylsilylm ethyl-substituted disilacyclohexanes and trialkylsilylm ethyl-substituted disilacyclopentanes. The ratio of six-membered to five-membered ring products obtained is dependent on the linking group X and decreased in the order X=O>CH~2~>NH>NCH~3~. For X = NSiMe~3~ only a mixture of the cis and trans isomers of the five-membered ring product was obtained.

Who reads Radical-Initiated Hydrosilylation-Cyclization Reactions of Bis(vinyldimethylsilyl) Compounds, CH~2~=CH(CH~3~)~2~SiXSi(CH~3~)~2~CH=CH~2~ (X = O, CH~2~, NH, NCH~3~, NSi?

Author

Dietmar Seyferth; Holger Friedrich; Shane W. Krska

Publisher

Walter de Gruyter GmbH

Published

1994

Language

EN

Field

Chemistry (Physical Sciences)