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Tuning the structural and photophysical behaviour of non-toxic CsSnCl3 using reduced graphene oxide for optoelectronic applications by Ajay Kumar; Nivedita Pandey; Deepak Punetha; Rajib Saha; Subhananda Chakrabarti is a scholarly article available to read on EtoBox.
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The non-toxic metal halide-based perovskite materials can be a greener alternative to leadbased perovskites because of their stability and high-scale production. Herein, we have tuned the structural and photophysical behaviour of non-toxic halide-based perovskite CsSnCl3 by forming a heterostructure with reduced graphene oxide (rGO) owing to its high carrier mobility and thermal conductivity. The crystal structure of CsSnCl3 and CsSnCl3/rGO heterostructure has been analyzed using the X-ray diffraction (XRD) technique which confirms the formation of a highly crystalline cubic phase. The high absorption behaviour of CsSnCl3 and CsSnCl3/rGO can be clearly seen from the ultraviolet-visible (UV-vis) spectrum. A direct bandgap of 3.24 eV and 3.19 eV has been calculated from the Tauc plot for CsSnCl3 and CsSnCl3/rGO heterostructure respectively. The Photoluminescence (PL) plot shows a high quenching blue shift phenomenon in CsSnCl3/rGO heterostructure as compared to pristine CsSnCl3 material due to the faster separation and transfer of charges from photogenerated electron-hole pairs. Further, the surface morphology of CsSnCl3 and rGO/CsSnCl3 heterostructure has been noticed by utilizing t
- Author
- Ajay Kumar; Nivedita Pandey; Deepak Punetha; Rajib Saha; Subhananda Chakrabarti
- Publisher
- SPIE
- Published
- 2023
- Language
- EN
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