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Can I read Synthetic reactions by complex catalysts—XXI on EtoBox?
Synthetic reactions by complex catalysts—XXI by T. Saegusa; I. Murase; Y. Ito is a Chemistry article available to read on EtoBox.
What is Synthetic reactions by complex catalysts—XXI about?
Ah&ad-Two groups of reactions of ally1 isocyanide in the presence ofcoppcr (I), namely the double-bond isome~zation of ally! isocyanide (AK) to propenyl isocyanide (PPIC) (eq. I), and formimidations of amide, amine and alcohol with AX are described. The reaction of N-alkylamide with AIC gave the product by the insertion of the isocyanide carbon atom of PPIC into the \ / N-H bond of amide (eq. 3). In the fo~imidation of secondary amine with AIC, the AIC isomerization occurs concurrently, and two products (I3 and 14) are formed. The reaction of alcohol with AIC gave the product by 1,4-addition of the second molecule of alcohol to the primary formimidation product.
Who reads Synthetic reactions by complex catalysts—XXI?
It is typically read by researchers, students, and practitioners in Chemistry.
- Author
- T. Saegusa; I. Murase; Y. Ito
- Publisher
- Elsevier Science; Elsevier ; Elsevier Ltd.; Elsevier BV (ISSN 0040-4020)
- Published
- 1971
- Language
- EN
- Field
- Chemistry (Physical Sciences)