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Development of a catalytic cycle for the generation of C1-glycosyl carbanions with Cp2TiCl2: application to glycal synthesis by Thomas Hansen; Kim Daasbjerg; Troels Skrydstrup is a scholarly article available to read on EtoBox.

What is Development of a catalytic cycle for the generation of C1-glycosyl carbanions with Cp2TiCl2: application to glycal synthesis about?

A catalytic cycle has been developed for the conversion of glycosyl halides to their corresponding glycals using Cp 2 TiCl 2 . This process can be effectively used with only 30% of the in situ generated single electron reducing agent in contrast to the 2 equivalents normally employed.

Author

Thomas Hansen; Kim Daasbjerg; Troels Skrydstrup

Publisher

Elsevier Science; Elsevier ; Elsevier Ltd.; Elsevier BV (ISSN 0040-4039)

Published

2000

Language

EN