Can I read Theoretical analysis of the influence of the adsorption process on the voltammetric curves in the case of a second order adsorption step followed by a first order charge transfer reaction: Part III. Variation of the transfer coefficient and application to semiconductor electrodes in l.p.s.v. and s.s.c.v. on EtoBox?

Theoretical analysis of the influence of the adsorption process on the voltammetric curves in the case of a second order adsorption step followed by a first order charge transfer reaction: Part III. Variation of the transfer coefficient and application to semiconductor electrodes in l.p.s.v. and s.s.c.v. by Anne-Marie Alquie-Redon; Jacky Vigneron; Claude Lamy is a Chemistry article available to read on EtoBox.

What is Theoretical analysis of the influence of the adsorption process on the voltammetric curves in the case of a second order adsorption step followed by a first order charge transfer reaction: Part III. Variation of the transfer coefficient and application to semiconductor electrodes in l.p.s.v. and s.s.c.v. about?

The kinetic behaviour of a two-step sequential reaction including a 2nd order adsorption process is treated theoretically in the case of semiconductor electrodes. It is shown that the electronic structure of the semiconductor can be taken into account in some simplified cases by introducing a formal transfer coefficient comprised between 0 and 1 and potential independent. In both linear potential sweep voltammetry and steady state cyclic voltammetry, the usual characteristic fdatures (EM, 0M, iM) of the voltammetric curves are calculated as a function of the sweep rate for different values of the transfer coefficient. \* These extensions have been suggested by the referee to whom we are indebted.

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Author

Anne-Marie Alquie-Redon; Jacky Vigneron; Claude Lamy

Publisher

Elsevier Science; Elsevier ; Elsevier BV (ISSN 0022-0728)

Published

1978

Language

EN

Field

Chemistry (Physical Sciences)