Can I read Cross-metathesis Reaction of Vinyl Sulfones and Sulfoxides on EtoBox?
Cross-metathesis Reaction of Vinyl Sulfones and Sulfoxides by Anna Michrowska; Michał Bieniek; Mikhail Kim; Rafał Klajn; Karol Grela is a Chemistry article available to read on EtoBox.
What is Cross-metathesis Reaction of Vinyl Sulfones and Sulfoxides about?
Cross-metathesis reactions of a,b-unsaturated sulfones and sulfoxides in the presence of molybdenum and ruthenium precatalysts were tested. A selective metahesis reaction was achieved between functionalized terminal olefins and vinyl sulfones by using the 'second generation' ruthenium catalysts 1c-h while the highly active Schrock catalyst 1b was found to be functional group incompatible with vinyl sulfones. The cross-metathesis products were isolated in good yields with an excellent (E)-selectivity. Both the molybdenum and ruthenium-based complexes were, however, incompatible with a,band b,g-unsaturated sulfoxides.
Who reads Cross-metathesis Reaction of Vinyl Sulfones and Sulfoxides?
It is typically read by researchers, students, and practitioners in Chemistry.
- Author
- Anna Michrowska; Michał Bieniek; Mikhail Kim; Rafał Klajn; Karol Grela
- Publisher
- Elsevier Science; Elsevier ; Elsevier Ltd.; Elsevier BV (ISSN 0040-4020)
- Published
- 2003
- Language
- EN
- Field
- Chemistry (Physical Sciences)