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Effect of ionic liquid on polyaniline chemically synthesised under falling-pH conditions by Anurag Krishna; Cosmin Laslau; Geoffrey Waterhouse; Zoran Zujovic; Jadranka Travas-Sejdic is a Chemistry article available to read on EtoBox.
What is Effect of ionic liquid on polyaniline chemically synthesised under falling-pH conditions about?
## Abstract This study investigates the effect of the ionic liquid 1-butyl-3-methyl imidazolium chloride ([bmim]Cl) on the morphological, structural, and electronic properties of polyaniline (PANI) products synthesised by the falling-pH method. Products were characterised by SEM, FT-IR, UVVIS, N2-physisorption, and conductivity measurements. The [bmim]Cl addition strongly influenced the PANI morphology, specific surface area, porosity, and conductivity. Depending on the [bmim]Cl: ANI ratio and the synthesis pH, a wide range of PANI nanostructures could be prepared, with rod-like, and fibre-like elongated structures being the dominant morphology under most experimental conditions. Samples prepared in the presence of [bmim]Cl exhibit specific areas of ca 22–35 m2 g−1. The conductivity of the final products depends on the [bmim]Cl: ANI ratio. Temperature dependence of conductivity in the temperature range from 77 K to 300 K was also studied.
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- Author
- Anurag Krishna; Cosmin Laslau; Geoffrey Waterhouse; Zoran Zujovic; Jadranka Travas-Sejdic
- Publisher
- Versita; Springer-Verlag; Springer International Publishing AG; Bratislava: Institute of Chemistry Slovak Academy of Sciences; Warszawa: Versita; Heidelberg: Springer, 2006-2014.; Bratislava: Institute of Chemistry Slovak Academy of Sciences; Berlin: De Gruyter, 2015-2016.; Bratislava: Institute of Chemistry Slovak Academy of Sciences; Heidelberg: Springer, 2017-; Bratislava: Institute of Chemistry Slovak Academy of Sciences; Warszawa: De Gruyter, 2016-2016; Springer Science and Business Media LLC; Society for Mining, Metallurgy and Exploration Inc. (ISSN 0366-6352)
- Published
- 2013
- Language
- EN
- Field
- Chemistry (Physical Sciences)