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This study explores the use of Pd–Pb alloy nanocrystals (NCs) for semihydrogenation reactions, demonstrating that catalyst poisoning can be leveraged to control the shape and composition of the NCs. The incorporation of lead into palladium NCs results in enhanced selectivity for the semihydrogenation of phenylacetylene, surpassing the performance of traditional Lindlar catalysts. The findings suggest that the poisoning effect can be utilized as a strategic tool for tailoring catalyst properties in heterogen

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karenhtb14

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EN