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Suzuki Reactions with Stable Organic Radicals – Synthesis of Biphenyls Substituted with Nitronyl-Nitroxide Radicals by Christophe Stroh; Marcel Mayor; Carsten von Hänisch is a Chemistry article available to read on EtoBox.

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## Abstract The synthesis of biphenyls substituted with nitronyl‐nitroxide organic radicals is described. To investigate the Suzuki‐type cross‐coupling reaction conditions in the presence of the radical, a model compound **1** was prepared. The successful coupling was extended to cyano‐functionalized, biphenylic, paramagnetic molecules. Both the __ortho__‐ and __meta__‐iodophenyl‐nitronyl‐nitroxide radicals were used to synthesize radicals **2** and **3**. The characterizations of the spin‐labelled molecules obtained by this synthetic strategy include two X‐ray crystal structures and magnetic measurements. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2005)

Who reads Suzuki Reactions with Stable Organic Radicals – Synthesis of Biphenyls Substituted with Nitronyl-Nitroxide Radicals?

Author

Christophe Stroh; Marcel Mayor; Carsten von Hänisch

Publisher

John Wiley and Sons; Wiley (John Wiley & Sons); John Wiley & Sons Ltd.; Wiley (ISSN 1434-193X)

Published

2005

Language

EN

Field

Chemistry (Physical Sciences)