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The reaction of β-dicarbonyl compounds with trifluoromethylsulphenyl chloride. Part I. CF3S-substituted esters, anilides of β-keto acids, and their Schiff bases: Synthesis and stability. by A. Kolasa is a Chemistry article available to read on EtoBox.
What is The reaction of β-dicarbonyl compounds with trifluoromethylsulphenyl chloride. Part I. CF3S-substituted esters, anilides of β-keto acids, and their Schiff bases: Synthesis and stability. about?
The reactions of the p-keto acid derivatives with trifluoromethylsulphenyl chloride were carried out to give the &SCF3 substituted esters, anilides, and their Schiff bases of acetyl-and benzoylacetic acids. Ethyl esters of &-(trifluoromethylthio)acetoacetic and c+(trifluoromethylthio)benzoylacetic acids heated in dimethylsulphoxide/water solution give trifluoromethylthioacetone and ti-(trifluoromethylthio)acetophenone respectively, whereas with potassium hydroxide solution they form trifluoromethylthioacetic acid in a good yield.
Who reads The reaction of β-dicarbonyl compounds with trifluoromethylsulphenyl chloride. Part I. CF3S-substituted esters, anilides of β-keto acids, and their Schiff bases: Synthesis and stability.?
It is typically read by researchers, students, and practitioners in Chemistry.
- Author
- A. Kolasa
- Publisher
- Elsevier Science; Elsevier ; Elsevier BV (ISSN 0022-1139)
- Published
- 1987
- Language
- EN
- Field
- Chemistry (Physical Sciences)