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Synthesis of Nitro-Substituted Polyfunctional Biphenyls by Negishi Cross-Coupling of o-Nitroarylzinc Reagents by Ioannis Sapountzis; Henry Dube; Paul Knochel is a Chemistry article available to read on EtoBox.

What is Synthesis of Nitro-Substituted Polyfunctional Biphenyls by Negishi Cross-Coupling of o-Nitroarylzinc Reagents about?

## Abstract The iodine‐magnesium exchange reaction allows the preparation of polyfunctional arylmagnesium species bearing a nitro group in the __ortho__‐position. After transmetalation to the corresponding arylzinc compound, these organometallics undergo a palladium‐catalyzed Negishi cross‐coupling with various aryl iodides to provide polyfunctional biphenyls bearing nitro groups in moderate to good yields.

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Author
Ioannis Sapountzis; Henry Dube; Paul Knochel
Publisher
John Wiley and Sons; Wiley (John Wiley & Sons); John Wiley & Sons Ltd.; Wiley - V C H Verlag GmbbH & Co.; Wiley (ISSN 1615-4150)
Published
2004
Language
EN
Field
Chemistry (Physical Sciences)

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