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Kinetics of a Monomolecular Photoreaction in a Strongly Light-absorbing Solid Solution Exemplified by the Forward Reaction of the Optically Switchable O-thiobenzoquinone Methide⇌benzo[b]thiete System by Christian Drohm; Hermann Meyer; Armin Schweig is a Physics and Astronomy article available to read on EtoBox.

What is Kinetics of a Monomolecular Photoreaction in a Strongly Light-absorbing Solid Solution Exemplified by the Forward Reaction of the Optically Switchable O-thiobenzoquinone Methide⇌benzo[b]thiete System about?

The kinetics of the photobleaching process o-thiobenzoquinone methide (1)~ benzo[b]thiete (2), i.e. the forward reaction of the optically switchable 1 ~ 2 system, in a solid argon layer has been investigated experimentally by measuring the time-dependent photon flux density (photon irradiance) of the transmitted photolysis light. A kinetic model is presented which simultaneously accounts for both the anisotropy of the light absorption and variation of the photon flux density in the layer with position and time. Good agreement between theory and experiment is achieved.

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Author

Christian Drohm; Hermann Meyer; Armin Schweig

Publisher

Elsevier Science; Elsevier ; Elsevier BV (ISSN 0009-2614)

Published

1995

Language

EN

Field

Physics and Astronomy (Physical Sciences)