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Switching the Solubility of PMMA Bearing Attached Cyclodextrin‐Moieties by Supramolecular Interactions with Ionic Liquids by Sadik Amajjahe; Maricica Munteanu; Helmut Ritter is a Materials Science article available to read on EtoBox.
What is Switching the Solubility of PMMA Bearing Attached Cyclodextrin‐Moieties by Supramolecular Interactions with Ionic Liquids about?
## Abstract Methacrylate‐modified __β__‐cyclodextrin (__β__‐CD) and methyl methacrylate (MMA) have been radically copolymerized to obtain hydrophobic CD copolymers. The water‐insoluble copolymers are able to form highly stable inclusion complexes with anions of ionic liquids. Surprisingly, the inclusion of the anions in the CD cavity results in a significant change of thermal and solution properties. Furthermore, it can be shown that the structure of the ionic liquid anions influences the coil structure of the copolymers. The obtained results could be proven by means of microcalorimetry, differential scanning calorimetry, and dynamic light scattering. magnified image
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It is typically read by researchers, students, and practitioners in Materials Science.
- Author
- Sadik Amajjahe; Maricica Munteanu; Helmut Ritter
- Publisher
- John Wiley and Sons; Wiley (John Wiley & Sons); John Wiley & Sons Ltd.; Wiley (ISSN 1022-1336)
- Published
- 2009
- Language
- EN
- Field
- Materials Science (Physical Sciences)