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Chromium Imine and Amine Complexes as Homogeneous Catalysts for the Trimerisation and Polymerisation of Ethylene by Martin E. Bluhm; Olaf Walter; Manfred Döring is a Chemistry article available to read on EtoBox.

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Cr(III) complexes of tridendate imine and amine ligands with N, P, O, S donor atoms 1 and 2 have been prepared and tested as catalysts in the oligomerisation and polymerisation of ethylene giving excellent selectivity towards 1-hexene and polymerisation to polyethylene when activated with cocatalysts. X-ray structure analyses of the precatalysts 1a-c, 1i, and 2b are investigated. The metal-ligand binding in 1a and 1b is nearly the same, which leads to similar catalytic activities of these precatalysts.

Who reads Chromium Imine and Amine Complexes as Homogeneous Catalysts for the Trimerisation and Polymerisation of Ethylene?

Author

Martin E. Bluhm; Olaf Walter; Manfred Döring

Publisher

Elsevier Science; Elsevier ; Elsevier BV (ISSN 0022-328X)

Published

2005

Language

EN

Field

Chemistry (Physical Sciences)