Opening book details…
Can I read Na2S2O4/NaHCO3-system promoted addition-cyclization of per( poly)fluoroalkyl iodides or perhaloalkanes with 1,6-heptadienes on EtoBox?
Na2S2O4/NaHCO3-system promoted addition-cyclization of per( poly)fluoroalkyl iodides or perhaloalkanes with 1,6-heptadienes by Gang Zhao; Jin Yang; Wei-yuan Huang is a Chemistry article available to read on EtoBox.
What is Na2S2O4/NaHCO3-system promoted addition-cyclization of per( poly)fluoroalkyl iodides or perhaloalkanes with 1,6-heptadienes about?
An efficient and practical synthetic method for the preparation of five-membered ring compounds is reported. Carbocyclic and heterocyclic five-membered ring compounds bearing polyfluoroalkyl groups were obtained using Na&O,/NaHCO, promoted addition-cyclization of per( poly) Huoroalkyl iodides or perhaloalkanes with I ,h-heptadienes. The stereochemistry of hydrodehalogenation products (5.6,8,9) was determined based on their 'H-NMR spectra. y-Lactams and y-lactones bearing fluoroalkyl groups were obtained using the same system promoted per(poly)fluoroalkylation reaction with N-ally1 acrylamides (10) and ally1 propiolate (15) under similar reaction conditions.
Who reads Na2S2O4/NaHCO3-system promoted addition-cyclization of per( poly)fluoroalkyl iodides or perhaloalkanes with 1,6-heptadienes?
It is typically read by researchers, students, and practitioners in Chemistry.
- Author
- Gang Zhao; Jin Yang; Wei-yuan Huang
- Publisher
- Elsevier Science; Elsevier ; Elsevier BV (ISSN 0022-1139)
- Published
- 1997
- Language
- EN
- Field
- Chemistry (Physical Sciences)