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Bipolar Membranes in Forward Bias Region for Fuel Cell Reactors by Elena Lobyntseva; Tanja Kallio; Kyösti Kontturi is a Engineering article available to read on EtoBox.

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Three bipolar membranes, two home-made composed of commercial cation (DuPont) and anion (FuMA-Tech) exchange membranes (called Nafion/FT-FAA and Nafion/FT-FAS) and a commercial one, BP-1 from FuMA-Tech, were investigated in order to characterize their suitability to use in a H 2 /O 2 fuel cell intended to produce hydrogen peroxide on the cathode instead of water. The Nafion/FT-FAA and Nafion/FT-FAS membranes were prepared using a hot-pressing method. The optimal hot-pressing conditions were determined by measuring the ionic conductivity of the membranes. The latter was observed to depend on the relative humidity of the bipolar membrane. Of the studied bipolar membranes, Nafion/FT-FAA showed the best performance. The transport number of protons measured in a concentration cell was observed to depend on the direction of the proton diffusion flux through these membranes so that transport numbers of ca. unity were obtained when the cation exchange side faced the solution with higher proton concentration. In the opposite case, when the higher concentration faced anion exchange side, the transport number of proton was clearly lower, indicating the usefulness of the bipolar membranes for

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Author

Elena Lobyntseva; Tanja Kallio; Kyösti Kontturi

Publisher

Elsevier Science; Elsevier ; Elsevier Ltd.; Elsevier BV (ISSN 0013-4686)

Published

2006

Language

EN

Field

Engineering (Physical Sciences)