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Synthesis, Characterization, and Energetic Properties of Nitroso Compounds by Dr. Carles Miró Sabaté; Henri Delalu is a Chemistry article available to read on EtoBox.
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## Abstract Sodium and potassium methyl(nitroso)amide (__M__[CH~3~N~2~O], __M__ = Na (1), K (2)) were prepared by the reaction of monomethylhydrazine with iso‐pentyl nitrite or __n__‐butyl nitrite and a suitable metal ethoxide (__M__[CH~3~CH~2~O], __M__ = Na, K) in an ethanol‐ether mixture. The reaction of monomethylhydrazine with a small excess of iso‐pentyl nitrite or __n__‐butyl nitrite and in the absence of a metal ethoxide led to the formation of __N__‐nitroso‐__N__‐methylhydrazine (CH~3~(NO)N–NH~2~, (3)). Alternatively, compound 3 was prepared by the amination reaction of 1 or 2 using the sodium salt of HOSA in ethanol solution. Compounds 1–3 were characterized using elemental analysis, differential scanning calorimetry, mass spectrometry, vibrational (infrared and Raman) and UV spectroscopy and multinuclear (^1^H, ^13^C and ^15^N) NMR spectroscopy. For compounds 1–3, several physical and chemical properties of interest and sensitivity data were measured and for compound 3 thermodynamic and explosive properties are also given. Additionally, the solid‐state structure of compound 3 was determined by single‐crystal X‐ray analysis and the structures of the __cis__‐ and __trans__‐
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- Author
- Dr. Carles Miró Sabaté; Henri Delalu
- Publisher
- John Wiley and Sons; Wiley (John Wiley & Sons); Wiley - V C H Verlag GmbbH & Co.; Wiley (ISSN 0372-7874)
- Published
- 2011
- Language
- DE
- Field
- Chemistry (Physical Sciences)