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Analysis of the linear methods of determining copolymerization reactivity ratios, 12. Copolymerization of styrene or methyl methacrylate with N ‐ p ‐tolylcitraconimide or fumarodinitrile by Braun, Dietrich ;Czerwinski, Wojciech K. ;Bednarski, Ralf ;Tüdős, Ferenc ;Kelen, Tibor is a Chemistry article available to read on EtoBox.
What is Analysis of the linear methods of determining copolymerization reactivity ratios, 12. Copolymerization of styrene or methyl methacrylate with N ‐ p ‐tolylcitraconimide or fumarodinitrile about?
## Abstract For copolymerization of styrene or methyl methacrylate with __N__‐__p__‐tolylcitraconimide (in toluene) or fumarodinitrile (in benzene) at 60°C with 2,2′‐azoisobutyronitrile (AIBN) as initiator, the composition of the resulting copolymers was measured as a function of the monomer feed composition. To provide good accuracy of reaction modelling in terms of the terminal and penultimate models, the linearized forms of both models were applied assuring high sensitivity of the evaluation. Among the systems considered the styrene/fumarodinitrile system with __r__′~1~/__r__′~1~ ≈ 10 was found to copolymerize according to the penultimate mechanism to a significant degree.
Who reads Analysis of the linear methods of determining copolymerization reactivity ratios, 12. Copolymerization of styrene or methyl methacrylate with N ‐ p ‐tolylcitraconimide or fumarodinitrile?
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- Author
- Braun, Dietrich ;Czerwinski, Wojciech K. ;Bednarski, Ralf ;Tüdős, Ferenc ;Kelen, Tibor
- Publisher
- Wiley (John Wiley & Sons); Wiley (ISSN 0025-116X)
- Published
- 1992
- Language
- EN
- Field
- Chemistry (Physical Sciences)