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Stereoselective Synthesis of Bicyclo[4.2.1]nonanes – a Temporary-Bridge Approach to Cyclooctanoids by Antoine Michaut; Sonia Miranda-García; J. Carlos Menéndez; Yoann Coquerel; Jean Rodriguez is a Chemistry article available to read on EtoBox.
What is Stereoselective Synthesis of Bicyclo[4.2.1]nonanes – a Temporary-Bridge Approach to Cyclooctanoids about?
## Abstract A series of __cis__‐α,γ‐difunctionalized five‐membered cyclic β‐oxo esters have been chemo‐, regio‐ and diastereoselectively prepared through an efficient domino anionic ring‐cleavage/ring‐reconstitution/alkylation sequence including a 1,3‐shift of the ester group. These unsaturated substrates were successfully engaged in various ring‐closing metatheses to provide a reliable access to functionalized bicyclo[4.2.1]nonanes, precursors of cyclooctanoids following the selective fragmentation of the one‐carbon bridge.(© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2008)
Who reads Stereoselective Synthesis of Bicyclo[4.2.1]nonanes – a Temporary-Bridge Approach to Cyclooctanoids?
It is typically read by researchers, students, and practitioners in Chemistry.
- Author
- Antoine Michaut; Sonia Miranda-García; J. Carlos Menéndez; Yoann Coquerel; Jean Rodriguez
- Publisher
- John Wiley and Sons; Wiley (John Wiley & Sons); John Wiley & Sons Ltd.; Wiley (ISSN 1434-193X)
- Published
- 2008
- Language
- EN
- Field
- Chemistry (Physical Sciences)