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Theoretical consideration on phase behaviors of poly(ethylene oxide-block-propylene oxide)/LiCF3SO3 systems in lithium battery by Sung Jin Ko; Sun Joon Kim; Sung Ho Kong; Young Chan Bae is a Engineering article available to read on EtoBox.

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A new thermodynamic model is developed based on the extended perturbed hard sphere chain (PHSC) model and melting point depression theory to describe the phase behaviors of copolymer electrolyte/salt systems. The phase behaviors of poly(ethylene oxide-block-propylene oxide)/LiCF 3 SO 3 systems are investigated by thermo-optical analysis (TOA) technique. Quantitative descriptions according to the proposed model are in good agreement with experimental data. The obtained results show that monomer ratio and sequence type of copolymers play a great role in determining eutectic points of the given systems.

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Author

Sung Jin Ko; Sun Joon Kim; Sung Ho Kong; Young Chan Bae

Publisher

Elsevier Science; Elsevier ; Elsevier Ltd.; Elsevier BV (ISSN 0013-4686)

Published

2004

Language

EN

Field

Engineering (Physical Sciences)