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The Structure of Artabsin by T.A. Geissman; T.E. Winters is a Chemistry article available to read on EtoBox.

What is The Structure of Artabsin about?

The sesquiterpene lactone artabsin, from Artemisia absinthium L., has been assigned the structure I on the basis of its relationship to isophotosantonic lactone and a degradation sequence which led to the placing of the double bonds as shown. (2,3) We have examined a specimen of 4. absinthium L. collected in Pullman, Washington, (4) the authenticity of which is supported by our isolation of artemetin (5-hydroxy-3,6,7,3',4'-tetramethoxy flavone), which has been found in this species in several previous studies. ( 5) A sesquiterpene lactone, isolated in about 0.1% yield, had properties indicating that it was the artabsin described earlier (2) (and which was at that time also isolated in 0.1% yield). Our compound had the composition C15H2003, m.p. 131-133", Amax 248 mu (log s 3.49),

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Author
T.A. Geissman; T.E. Winters
Publisher
Elsevier Science; Elsevier ; Elsevier Ltd.; Elsevier BV (ISSN 0040-4039)
Published
1968
Language
EN
Field
Chemistry (Physical Sciences)

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