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Photo-crosslinked Fluorinated Thin Films from Azido-functionalized Random Copolymers by Samer Al Akhrass; Denis Damiron; Géraldine Carrot; Eric Drockenmuller is a Materials Science article available to read on EtoBox.

What is Photo-crosslinked Fluorinated Thin Films from Azido-functionalized Random Copolymers about?

## Abstract Random copolymers of styrene, __p__‐azidomethylstyrene and 1H,1H,2H,2H‐perfluorodecyl methacrylate were prepared in two steps involving nitroxide‐mediated radical copolymerization and azidation reaction and further characterized by ^1^H and ^19^F NMR, size exclusion chromatography, differential scanning calorimetry, and thermal gravimetric analysis. Ultrathin films of these azidomethyl‐functionalized fluorinated random copolymers, with thicknesses ranging from 20 to 100 nm, were spin coated onto Si substrates and then crosslinked by ultraviolet irradiation resulting in smooth and insoluble crosslinked fluorinated polymer mats. The surface properties of the supported thin films were investigated by X‐ray photoelectron spectroscopy and water contact angle measurements. These tailored photo‐crosslinked coatings afford a versatile control and homogenization of the wetting properties of different organic and inorganic substrates. © 2010 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 48: 3888–3895, 2010

Who reads Photo-crosslinked Fluorinated Thin Films from Azido-functionalized Random Copolymers?

Author

Samer Al Akhrass; Denis Damiron; Géraldine Carrot; Eric Drockenmuller

Publisher

John Wiley and Sons; Wiley (John Wiley & Sons); John Wiley & Sons Inc.; Wiley (ISSN 0887-624X)

Published

2010

Language

EN

Field

Materials Science (Physical Sciences)