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Synthesis and characterization of bis(2,2′-bipyridine)(camphorquinone monoximato)ruthenium(II) perchlorate monohydrate by Sutapa Sinha; Pradyut Kumar Das; Barindra Kumar Ghosh is a Chemistry article available to read on EtoBox.

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The electrophilic addition of cis-[RuC1(NO)(bipy),12+ (bipy = 2,2'-bipyridine) to camphor in boiling methanol containing sodium methoxide affords the new complex [Ru(A)(bipy),]+ (1) (A = anion of camphorquinone monoxime). An alternative synthesis of 1 is provided by the reaction of cis-RuCl, (bipy), with HA. The cation is isolated as crystalline perchlorate monohydrate. The diamagnetic complex displays an intense metalto-ligand charge-transfer transition at ca 440 nm. A reversible ruthenium(III)ruthenium(I1) couple near 0.8 V and two diimine reductions on the negative side of SCE are observed.

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Author

Sutapa Sinha; Pradyut Kumar Das; Barindra Kumar Ghosh

Publisher

Elsevier Science; Elsevier ; Elsevier Ltd.; Elsevier BV (ISSN 0277-5387)

Published

1994

Language

EN

Field

Chemistry (Physical Sciences)