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Synthesis, Crystal Structure, IR Spectra and Thermal Analysis of Na[Ag(sac)~2~] (sac = saccharinate) by Veysel T. Yilmaz; Sevim Hamamci; Carsten Thöne is a Chemistry article available to read on EtoBox.

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## Abstract The reaction of silver nitrate with sodium saccharinate (Na[sac]) in the presence of 2‐pyridinepropanol in aqueous solution yields the title complex, Na[Ag(sac)~2~]. The compound crystallizes in the triclinic space group $P {\bar 1}$ [a = 8.0481(6), b = 9.0587(6), c = 11.1642(8) Å; α = 100.064(3), __β__ = 99.917(3) and γ = 92.367(3)°, Z = 2]. The structure consists of Na^+^ and [Ag(sac)~2~]^‐^ ions, in which each silver(I) ion is doubly bridged by the sac ligands, exhibiting a distorted 'T' shaped AgN~2~O coordination arrangement with one long [Ag‐O~sulfonyl~ = 2.6390(10) Å] and two shorter bonds [Ag‐N = 2.1405(11) and 2.1570(11) Å]. The coordination around silver(I) is trigonal planar and the N‐Ag‐N bond angle is 158.99(5)°. The Na^+^ ion is five‐coordinate with two carbonyl and three sulfonyl O atoms of the adjacent sac ligands and acts as a bridge between [Ag(sac)~2~]^‐^ units, resulting in a three‐dimensional network. The i.r. spectra and thermal decomposition behaviour of Na[Ag(sac)~2~] are discussed in detail.

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Author

Veysel T. Yilmaz; Sevim Hamamci; Carsten Thöne

Publisher

John Wiley and Sons; Wiley (John Wiley & Sons); Wiley - V C H Verlag GmbbH & Co.; Wiley (ISSN 0372-7874)

Published

2004

Language

EN

Field

Chemistry (Physical Sciences)