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SuIt soldiotis; Iloiliiig point ofitndcr varying prcasursu. E. 3C. Unkcr and \'. 1-1. Wtiitc. Anicr. h t . Chcm. l h g . , 21.6.21. Clieni. and Not. A KNOJVLEIICE of tho hoiling point of salt solutions iindcr rculiicd pressiirc is irnportnnt in cvaporntor clcsign. hii apparittus t o ohtatin such data with n ninsimiini nbsoluto crror of @lo G'. is dcscrikd. TI10 tenipcrnturo is nicnsured by n plntinuni resistnnco thcriiionicter in tho vnpour spnco but constantly wcttccl with solution, tho Iionting is clectricnl, iind tho prcssuro is licpt uniform by :in niitornntic clwtricnl rcgiil:itor. Results nrc tnbiihted sliowiiig tlint unsatrirntctl solutioiis i n wliicli tho cnpour prewiro of tho solute is innp~irccinblu follow 1)iiliring's rule within t Iic liiiiits of tlio aliorc error, i.c., if t I :iiicl t , iiro tho boiling points of n solution n t prcssurcs p i , nnd p , , nncl 0 , arid 0, the boiling points of w;rter :it tlicsc pressures, then ( t , -t , ) = K (0,-U,), K being : I constnnt for a g v c n fioliition. llciicc to obt:iin n coniplcto boiling-point curve for any solution orily two detcrniirintioiis, one lieing at xtmosplicric pressure, nro necessary. Cdciuiit chloride-icuf e

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Publisher

Wiley (John Wiley & Sons); Wiley (ISSN 0368-4075)

Published

1922

Language

EN

Field

Chemistry (Physical Sciences)