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This document describes a kinetic study of the free radical polymerization of acrylonitrile initiated by the chloramine-T/hydrogen peroxide redox system in an aqueous medium. The effects of variations in monomer concentration, chloramine-T concentration, hydrogen peroxide concentration, temperature, and chloramine-T disappearance on the rate of polymerization were measured. A reaction scheme is proposed based on the kinetic results, and thermodynamic parameters and molecular weights of the polyacrylonitrile

Author

Trường Tùng Lý

Language

EN