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Polarized light study of the CsHSO4 and CsDSO4 superprotonic crystals by L Kirpichnikova; M Polomska; J Wolak; B Hilczer is a Materials Science article available to read on EtoBox.

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The results of an optical polarization study of superprotonic CsHSO and CsDSO crystals in the vicinity of phase 4 4 transitions are presented. Our observations allow us to state that the temperature of III-II phase transition in 'fresh', high quality crystals is 373 K. The temperature of the phase transition of the specimens that have experienced the III-II phase transition earlier is reduced to 330 K. It is established that changes of the domain structure in CsDSO crystals are observed 4 on both increasing and decreasing temperature at 3 K away from the temperature of the superprotonic phase transition. The appearance of the new structure is accompanied by a gradual increase in the conductivity by 1.5-2 order of magnitude and then the conductivity increases abruptly by another two orders of magnitude at the temperature of the superprotonic phase transition.

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Author

L Kirpichnikova; M Polomska; J Wolak; B Hilczer

Publisher

Elsevier Science; Elsevier ; Elsevier BV (ISSN 0167-2738)

Published

1997

Language

EN

Field

Materials Science (Physical Sciences)