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Magnetic interactions in the compounds Fe0.33NbTiP3O12, Sn0.5NbTiP3O12 and Mn0.5NbTiP3O12 by Frank J. Berry; José F. Marco; Javier Tejada; Ferran Badia is a Chemistry article available to read on EtoBox.

What is Magnetic interactions in the compounds Fe0.33NbTiP3O12, Sn0.5NbTiP3O12 and Mn0.5NbTiP3O12 about?

The reaction of elemental iron, tin and manganese with the white diamagnetic niobium titanium phosphorus oxide NbTiP,O , 2 produces blue-black compounds of com-. . posltlon Fe,,33NbTiP30 1 2, Sn,,5NbTiP301 2 and Mno,sNbTiP30 1 2. Magnetic susceptibility and MGssbauer spectroscopy measurements show the blue-black compounds to be paramagnetic over the temperature range 4.2-298 K. The magnetic properties are associated with the incorporation of paramagnetic metallic cations within the three-dimensional interspace of NbTiP30, 2 and the concomitant reduction of cations in the host structure.

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Author

Frank J. Berry; José F. Marco; Javier Tejada; Ferran Badia

Publisher

Elsevier Science; Elsevier ; Elsevier Ltd.; Elsevier BV (ISSN 0277-5387)

Published

1992

Language

EN

Field

Chemistry (Physical Sciences)