Can I read Cobaltacarboranes with Intramolecular Monophosphorus Bridges 8,8'-μ-Me2P(1,2-C2B9H10)2-3-Co, 6,6'-μ-Me2P(1,7-C2B9H10)2-2-Co and the Respective Non-Bridged Trimethylphosphine Derivatives (8-Me3P-1,2-C2B9H10)-3-Co-(1,2-C2B9H11) and (6-Me3P-1,7-C2B9H10)-2-Co-(1,7-C2B9H11) on EtoBox?

Cobaltacarboranes with Intramolecular Monophosphorus Bridges 8,8'-μ-Me2P(1,2-C2B9H10)2-3-Co, 6,6'-μ-Me2P(1,7-C2B9H10)2-2-Co and the Respective Non-Bridged Trimethylphosphine Derivatives (8-Me3P-1,2-C2B9H10)-3-Co-(1,2-C2B9H11) and (6-Me3P-1,7-C2B9H10)-2-Co-(1,7-C2B9H11) by Franken, Andreas; Plešek, Jaromír; Fusek, Jiří; Semrau, Markus is a Chemistry article available to read on EtoBox.

What is Cobaltacarboranes with Intramolecular Monophosphorus Bridges 8,8'-μ-Me2P(1,2-C2B9H10)2-3-Co, 6,6'-μ-Me2P(1,7-C2B9H10)2-2-Co and the Respective Non-Bridged Trimethylphosphine Derivatives (8-Me3P-1,2-C2B9H10)-3-Co-(1,2-C2B9H11) and (6-Me3P-1,7-C2B9H10)-2-Co-(1,7-C2B9H11) about?

The first two cobaltacarboranes with intramolecular phoshorus bridges and two related non-bridged trimethylphosphine-cobaltacarborane derivatives are described and characterized by mass spectrometry and multinuclear NMR; all four compounds are zwitterions: 8,8'-μ-Me2P(1,2-C2B9H10)2-3-Co (1a), 6,6'-μ-Me2P(1,7-C2B9H10)2-2-Co (2a), (8-Me3P-1,2-C2B9H10)-3-Co-(1,2-C2B9H11) (1b) and (6-Me3P-1,7-C2B9H10)-2-Co-(1,7-C2B9H11) (2b). X-Ray structures of the first two and of the last compound has been established.

Who reads Cobaltacarboranes with Intramolecular Monophosphorus Bridges 8,8'-μ-Me2P(1,2-C2B9H10)2-3-Co, 6,6'-μ-Me2P(1,7-C2B9H10)2-2-Co and the Respective Non-Bridged Trimethylphosphine Derivatives (8-Me3P-1,2-C2B9H10)-3-Co-(1,2-C2B9H11) and (6-Me3P-1,7-C2B9H10)-2-Co-(1,7-C2B9H11)?

Author

Franken, Andreas; Plešek, Jaromír; Fusek, Jiří; Semrau, Markus

Publisher

UOCHB; Institute of Organic Chemistry & Biochemistry, Academy of Sciences of the Czech Republic; Akademie Ved Ceske Republiky; Institute of Organic Chemistry & Biochemistry (ISSN 0010-0765)

Published

1997

Language

EN

Field

Chemistry (Physical Sciences)