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Stereocontrolled Synthesis of Cytotoxic Anhydrosphingosine Pachastrissamine by Using [3.3] Sigmatropic Rearrangement of Allyl Cyanate by Yoshiyasu Ichikawa; Kenshi Matsunaga; Toshiya Masuda; Hiyoshizo Kotsuki; Keiji Nakano is a Chemistry article available to read on EtoBox.
What is Stereocontrolled Synthesis of Cytotoxic Anhydrosphingosine Pachastrissamine by Using [3.3] Sigmatropic Rearrangement of Allyl Cyanate about?
A new route for the synthesis of the cytotoxic anhydrosphingosine pachastrissamine has been developed. [3.3] Sigmatropic rearrangement of an allyl cyanate was employed to construct the allyl amine moiety in 2 from the chiral C-4 unit 3. Oxidative cleavage of the double bond in 2, followed by THF ring formation furnished the target pachastrissamine.
Who reads Stereocontrolled Synthesis of Cytotoxic Anhydrosphingosine Pachastrissamine by Using [3.3] Sigmatropic Rearrangement of Allyl Cyanate?
It is typically read by researchers, students, and practitioners in Chemistry.
- Author
- Yoshiyasu Ichikawa; Kenshi Matsunaga; Toshiya Masuda; Hiyoshizo Kotsuki; Keiji Nakano
- Publisher
- Elsevier Science; Elsevier ; Elsevier Ltd.; Elsevier BV (ISSN 0040-4020)
- Published
- 2008
- Language
- EN
- Field
- Chemistry (Physical Sciences)