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Multiphoton ionization vibrational state selection of H2O+, D2O+ and HDO+ by Brady W. Uselman; Jason M. Boyle; Scott L. Anderson is a Physics and Astronomy article available to read on EtoBox.

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We present a study of single color (2 + 1) resonance-enhanced multiphoton ionization (REMPI) of H 2 O, D 2 O, and HDO via several Rydberg states lying in the energy range from 80 000 to 86 000 cm À1 . Photoelectron spectra (PES) show that the corresponding cations can be vibrationally state-selected for most vibrational states. The exception is the bend of H 2 O + and HDO + , where mixing in the REMPI intermediate level results in weak ion intensity and only $50% state purity.

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Author

Brady W. Uselman; Jason M. Boyle; Scott L. Anderson

Publisher

Elsevier Science; Elsevier ; Elsevier BV (ISSN 0009-2614)

Published

2007

Language

EN

Field

Physics and Astronomy (Physical Sciences)