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Visible light-driven photocatalyst: An iron(III) coordination compound in Rhodamine B degradation 1 1 Introduction 1 2 Experimental 2 2.1 Material and methods 2 2.2 Preparation of the complex [tris-(methyl 3-hydroxy-3-phenyl-2-propenedithioate-S,O)-iron(III)] [FeL3] 2 2.3 Preparation of the TiO2 thin film 2 2.4 Characterization of the thin films 2 2.5 Photocatalytic experiments 2 2.6 Photocatalytic reactions using Scavenger-type molecules. 2 3 Results and discussion 3 3.1 1 Preparation of the iron complex FeL3 3 3.2 Spectroscopic and structural evidence of the FeL3 formation 3 3.2.1 IR analyses of FeL3 complex 3 3.2.2 Raman analyses of FeL3 complex 3 3.2.3 TGA analysis of FeL3 complex 3 3.2.4 XPS analyses of FeL3 complex 5 3.2.5 XRD analyses of FeL3 complex 5 3.2.6 UV–vis analyses of FeL3 complex 5 3.3 The FeL3 supporting over glass or titania. 5 3.4 The band gap of the supported FeL3 complex 6 3.5 Isoelectric point 6 3.6 Catalytic performance of photocatalysts FeL3 6 3.7 The photodegradation mechanism of FeL3 8 4 Conclusions 9 CRediT authorship contribution statement 10 Declaration of Competing Interest 10 Acknowledgements 10 References 10

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nonfiction