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A Study Toward a Total Synthesis of Fostriecin by Yohei Kiyotsuka; Junji Igarashi; Yuichi Kobayashi is a Chemistry article available to read on EtoBox.

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In order to synthesize the major C(3) C( ) part of fostriecin, asymmetric dihydroxylation of several dienes 5a-f, prepared by cross-coupling reactions of several types, was studied, thus providing high dependency on the hydroxyl groups at C(5) and C(11). The best regioselectivity was obtained with 5d to produce diol 23, which was later transformed into the advanced intermediate 26.

Who reads A Study Toward a Total Synthesis of Fostriecin?

Author

Yohei Kiyotsuka; Junji Igarashi; Yuichi Kobayashi

Publisher

Elsevier Science; Elsevier ; Elsevier Ltd.; Elsevier BV (ISSN 0040-4039)

Published

2002

Language

EN

Field

Chemistry (Physical Sciences)