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Separation of the primary and secondary kinetic isotope effects at a reactive center using starting material reactivities. Application to the FeCl3-Catalyzed oxidation of CH bonds with tert-butyl hydroperoxide by Steven R. Merrigan; Valerie N. Le Gloahec; Jason A. Smith; Derek H.R. Barton; Daniel A. Singleton is a Chemistry article available to read on EtoBox.

What is Separation of the primary and secondary kinetic isotope effects at a reactive center using starting material reactivities. Application to the FeCl3-Catalyzed oxidation of CH bonds with tert-butyl hydroperoxide about?

A method is reported for the determination of both the primary and secondary kinetic isotope effects at a reactive center based on starting material reactivities. This allows the determination of the separate KIEs in reactions for which neither product analysis nor absolute rate measurements are applicable. The methodology is applied to the FeCl3-catalyzed oxidation of ethylbenzene with tert-butyl hydroperoxide, which exhibits both a primary isotope effect and a substantial secondary isotope effect.

Who reads Separation of the primary and secondary kinetic isotope effects at a reactive center using starting material reactivities. Application to the FeCl3-Catalyzed oxidation of CH bonds with tert-butyl hydroperoxide?

Author

Steven R. Merrigan; Valerie N. Le Gloahec; Jason A. Smith; Derek H.R. Barton; Daniel A. Singleton

Publisher

Elsevier Science; Elsevier ; Elsevier Ltd.; Elsevier BV (ISSN 0040-4039)

Published

1999

Language

EN

Field

Chemistry (Physical Sciences)