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The thermal degradation of poly(methyl acrylate). III. The mechanism of volatile formation by Cameron, G. G. ;Kane, D. R. is a Chemistry article available to read on EtoBox.
What is The thermal degradation of poly(methyl acrylate). III. The mechanism of volatile formation about?
The effects of the free radical inhibitor 1.4-diaminoanthraquinone on the evolution of carbon dioxide and methanol during the pyrolysis of poly(methy1 acrylate) have been studied. The experiments lead to the conelusion that these volatiles are formed in competing side processes of the free radical chain reaction which causes back bone fragmentation. I n the light of IR and UV spectroscopic measurements possible reaction routes are considered. ## ZUSAMMENFASSUNG: Bei der Pyrolyse von Polymethylacrylat wurde der EiduI3 des 1.4-Diaminoanthrachinons, eines Inhibitors fiir Radikalkettenreaktionen, auf die Bildung von Kohlendioxid und Methanol untersucht. Die Versuche fiihren zu dem SchluI3, daI3 diese fluchtigen Produkte aus Nebenreaktionen stammen, die mit der Kettenreaktion konkurrieren, die die Ursache fiir die Spaltung der Polymerhauptkette ist. Mogliche Reaktionswege werden an Hand von IR-und UV-Messungen diskutiert.
Who reads The thermal degradation of poly(methyl acrylate). III. The mechanism of volatile formation?
It is typically read by researchers, students, and practitioners in Chemistry.
- Author
- Cameron, G. G. ;Kane, D. R.
- Publisher
- Wiley (John Wiley & Sons); Wiley (ISSN 0025-116X)
- Published
- 1968
- Language
- EN
- Field
- Chemistry (Physical Sciences)