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Ternary Two‐Step Sequential Deposition Induced Perovskite Orientational Crystallization for High‐Performance Photovoltaic Devices by Chun‐Hao Chen; Yan‐Hui Lou; Kai‐Li Wang; Zhen‐Huang Su; Chong Dong; Jing Chen; Yi‐Ran Shi; Xing‐Yu Gao; Zhao‐Kui Wang is a Engineering article available to read on EtoBox.

What is Ternary Two‐Step Sequential Deposition Induced Perovskite Orientational Crystallization for High‐Performance Photovoltaic Devices about?

## Abstract State‐of‐the‐art, high‐performance formamidinium‐lead‐iodide‐based (FAPbI~3~‐based) perovskite photovoltaics are mainly prepared by one‐step antisolvent dripping deposition or two‐step sequential fabrication methods. Compared with the one‐step deposition, the two‐step fabricated perovskite films tend to grow columnar perovskite grains vertically which is easier for carrier extraction and transportation. Herein, the concept of formamidinium methylammonium cesium based ternary‐cation two‐step sequential deposition method is put forward by incorporating cesium acetate (CsAc) into a lead iodide precursor, which generates CsPbI~3~ crystal nuclei improving the further perovskite crystallization. When the formamidinium/methylammonium‐based organic amine salts solution is spin coated on the PbI~2~ substrate, the acetate moves upward and induces perovskite orientational and uniform crystallization, which can go a step further for the vertical columnar grains achieving fewer defects and higher photovoltaic efficiency. The champion outdoor power conversion efficiency of the modified device under AM 1.5G reaches 21.50% and its indoor efficiency at 1000 lux reaches 40.99%. This work

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Author
Chun‐Hao Chen; Yan‐Hui Lou; Kai‐Li Wang; Zhen‐Huang Su; Chong Dong; Jing Chen; Yi‐Ran Shi; Xing‐Yu Gao; Zhao‐Kui Wang
Publisher
Wiley
Published
2021
Language
EN
Field
Engineering (Physical Sciences)

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