Can I read Synthesis and Characterisation of New Arsonium Salts and Crystal Structures of Trimethylarsonium Undecafluorodiarsenate (CH3)3AsH+As2F11− and Trimethylarsonium Hexafluoroantimonate (CH3)3AsH+SbF6− on EtoBox?

Synthesis and Characterisation of New Arsonium Salts and Crystal Structures of Trimethylarsonium Undecafluorodiarsenate (CH3)3AsH+As2F11− and Trimethylarsonium Hexafluoroantimonate (CH3)3AsH+SbF6− by Rolf Minkwitz; Claudia Hirsch; Thorsten Berends is a Chemistry article available to read on EtoBox.

What is Synthesis and Characterisation of New Arsonium Salts and Crystal Structures of Trimethylarsonium Undecafluorodiarsenate (CH3)3AsH+As2F11− and Trimethylarsonium Hexafluoroantimonate (CH3)3AsH+SbF6− about?

The reaction of trimethylarsane in the superacidic systems As 2 F 11 -crystallizes in the monoclinic space group P2 1 /n with four formula units per unit cell with the dimensions a = hydrogen/fluoride antimony pentafluoride and hydrogen fluoride/arsenic pentafluoride leads to trimethylarsonium 7.362(1), b = 12.589(1), c = 13.598(1) A ̊and β = 95.37(1)°. (CH 3 ) 3 AsH + SbF 6 -crystallizes in the monoclinic space group fluorometallates. These salts are stable up to 60 °C and 5 °C, respectively. Structures were successfully elucidated in the P2 1 /m with four formula units per unit cell with the dimensions a = 8.313(1), b = 8.855(1), c = 13.285(1) A ̊and cases of trimethylarsonium undecafluorodiarsenate and trimethylarsonium hexafluoroantimonate. (CH 3

Who reads Synthesis and Characterisation of New Arsonium Salts and Crystal Structures of Trimethylarsonium Undecafluorodiarsenate (CH3)3AsH+As2F11− and Trimethylarsonium Hexafluoroantimonate (CH3)3AsH+SbF6−?

Author

Rolf Minkwitz; Claudia Hirsch; Thorsten Berends

Publisher

John Wiley and Sons; Wiley (John Wiley & Sons); John Wiley & Sons Ltd.; Wiley (ISSN 1434-1948)

Published

1999

Language

EN

Field

Chemistry (Physical Sciences)