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Hydrophosphination of Activated Alkenes by a Cobalt(I) Pincer Complex by Roberto Nolla‐Saltiel; Ana M. Geer; Laurence J. Taylor; Olivia Churchill; E. Stephen Davies; William Lewis; Alexander J. Blake; Deborah L. Kays is a Chemistry article available to read on EtoBox.
What is Hydrophosphination of Activated Alkenes by a Cobalt(I) Pincer Complex about?
## Abstract Herein we report the synthesis of three heteroleptic first‐row transition metal(II) complexes containing carbazolido NNN pincer ligands and conversion to the corresponding metal(I)‐carbonyl complexes via a reductive carbonylation route. These complexes are precatalysts for the hydrophosphination of activated alkenes, affording a cobalt‐catalysed hydrophosphination process that solely and selectively yields the β addition (anti‐Markovnikov) product. The scope of this transformation has been investigated using a variety of activated alkenes. Isolation and characterisation of substrate‐coordinated intermediates reveal available coordination sites, which provide insight into the proposed catalytic cycle. magnified image
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- Author
- Roberto Nolla‐Saltiel; Ana M. Geer; Laurence J. Taylor; Olivia Churchill; E. Stephen Davies; William Lewis; Alexander J. Blake; Deborah L. Kays
- Publisher
- John Wiley and Sons; Wiley (John Wiley & Sons); John Wiley & Sons Ltd.; Wiley - V C H Verlag GmbbH & Co.; Wiley (ISSN 1615-4150)
- Published
- 2020
- Language
- EN
- Field
- Chemistry (Physical Sciences)