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Aryl‐Aryl Coupling of Salicylic Aldehydes through Oxidative CH‐activation in Nickel Salen Derivatives by Andrei N. Yankin; Daniil A. Lukyanov; Evgenii V. Beletskii; Olga Yu. Bakulina; Petr S. Vlasov; Oleg V. Levin is a Chemistry article available to read on EtoBox.
What is Aryl‐Aryl Coupling of Salicylic Aldehydes through Oxidative CH‐activation in Nickel Salen Derivatives about?
## Abstract The preparative electrosynthetic procedure for gram‐scale preparation of symmetric 4,4′‐dihydroxy‐3,3′‐diformylbiphenyls from salicylic aldehydes __via__ the intermediate formation of ethylene‐bridged bis((2‐hydroxybenzylidene)imino)nickel (II) complexes is reported for the first time. This procedure represents a practical route to the variety of rare bisphenol derivatives. The electrochemical aryl‐aryl coupling __via__ an oxidative CH – activation in NiSalens is exploited for facile and selective C−C bond formation.
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- Author
- Andrei N. Yankin; Daniil A. Lukyanov; Evgenii V. Beletskii; Olga Yu. Bakulina; Petr S. Vlasov; Oleg V. Levin
- Publisher
- Wiley
- Published
- 2019
- Language
- EN
- Field
- Chemistry (Physical Sciences)