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Pulse radiolysis study on redox reactions of zinc(II) by M. Domae; N. Chitose; Z. Zuo; Y. Katsumura is a Materials Science article available to read on EtoBox.

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The radiation chemical reactions of zinc was investigated by pulse radiolysis technique. The rate constant k(e À aq +Zn(II)) was evaluated for several forms of Zn(II). The value of e 300 nm(Zn + ) was determined as (11,5002 500) dm 3 mol À1 cm À1 . The rate constants of several Zn + reactions were evaluated. The standard redox potentials (vs SHE) are estimated as following: À2.87 V <E 0 (Zn 2+ /Zn + ) +2.72 V. It is concluded that the zinc injection would have no negative eect on the radiolysis of the coolant in the light water nuclear reactors.

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Author

M. Domae; N. Chitose; Z. Zuo; Y. Katsumura

Publisher

Elsevier Science; Elsevier ; Elsevier Ltd.; Elsevier BV (ISSN 0969-806X)

Published

1999

Language

EN

Field

Materials Science (Physical Sciences)