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In situ growth and magnetic characterization of Cr Chloride monolayers by Buccoliero, Giuseppe; Pinho, Pamella Vasconcelos Borges; Cantarino, Marli Dos Reis; Rosa, Francesco; Brookes, Nicholas B.; Sant, Roberto is a scholarly article available to read on EtoBox.

What is In situ growth and magnetic characterization of Cr Chloride monolayers about?

Monolayer Chromium Dihalides and Trihalides materials can be grown on a variety of substrates by molecular beam epitaxy regardless of the lattice mismatch thanks to the van der Waals epitaxy. In this work, we studied the magnetic nature of Cr Chloride monolayers grown on Au(111), Ni(111) and graphene-passivated Ni(111) from the evaporation in ultra-high vacuum of the same halide precursor. Structural, morphological and magnetic characterizations were conducted in situ by low energy electron diffraction (LEED), scanning tunneling microscopy (STM) and X-ray magnetic circular dichroism (XMCD). Owing to opposite chemical behaviour, Au(111) and Ni(111) promote the formation of two different valence compounds, i.e. CrCl$_3$ and CrCl$_2$, showing distinct magnetic properties at 4 K. When graphene is used to passivate the Ni(111) surface, the formation of CrCl$_3$ becomes allowed also on this substrate. The coexistence of CrCl$_3$ and CrCl$_2$, both showing few nm lateral size and super-paramagnetic properties, is demonstrated by XMCD spectra displaying two dichroic peaks at the characteristic Cr$^{3+}$ and Cr$^{2+}$ energies. Site-selective magnetization measurements performed with the ph

Author

Buccoliero, Giuseppe; Pinho, Pamella Vasconcelos Borges; Cantarino, Marli Dos Reis; Rosa, Francesco; Brookes, Nicholas B.; Sant, Roberto

Published

2025

Language

EN