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Ba2B9O13F4·BF4: first fluorooxoborate with unprecedented infinite [B18O26F8] tubes and deep-ultraviolet cutoff edge by Huan Pei; Xuefei Wang; Jie Zhang; Fangfang Zhang; Zhihua Yang; Shilie Pan is a Engineering article available to read on EtoBox.

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Fluorooxoborate has emerged as a promising system for exploring optical materials due to their rich structural chemistry and physicochemical properties, yet so far not fully studied. Herein, we report a new fluorooxoborate, Ba 2 B 9 O 13 F 4 •BF 4 , which contains the greatest variety of structural basic units, and [BF 4 ], and exhibits unprecedented 1D infinite [B 18 O 26 F 8 ] tubes. The unique structure avoids the dangling bonds caused by terminal oxygens, which is beneficial to the large bandgap and deep-ultraviolet cutoff edge. This article expands the crystal structure of fluorooxoborates and contributes to the exploration of deep-ultraviolet optical materials in fluorooxoborate systems. fluorooxoborate, unprecedented infinite tubes, four basic units, deep-ultraviolet

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Author

Huan Pei; Xuefei Wang; Jie Zhang; Fangfang Zhang; Zhihua Yang; Shilie Pan

Publisher

Springer Science and Business Media LLC

Published

2023

Language

EN

Field

Engineering (Physical Sciences)