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Infrared and Near-infrared Spectroscopic Study of Synthetic Hydrotalcites with Variable Divalent/trivalent Cationic Ratios by Ray L. Frost; Henry J. Spratt; Sara J. Palmer is a Chemistry article available to read on EtoBox.

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Near-infrared (NIR), X-ray diffraction (XRD) and infrared (IR) spectroscopy have been applied to hydrotalcites of the formula Mg(6) (Fe,Al)(2)(OH)(16)(CO(3)).4H(2)O formed by intercalation with the carbonate anion as a function of divalent/trivalent cationic ratio. Such hydrotalcites were found to show variation in the d-spacing attributed to the size of the cation. In the IR (1750-4000cm(-1)), the position of all bands except those at approximately 3060cm(-1) shift to higher wavenumbers as the cation ratio increases. Conversely, at wavenumbers below 1000cm(-1), the bands shift to lower wavenumbers as the cation ratio increases. A water bending mode at higher wavenumbers was also observed which indicates that the water is strongly hydrogen bonded. In the NIR spectrum between 8000 and 12,000cm(-1), there is a broad feature which is attributed to electronic bands of the ferrous ion and low intensity sharp bands due to overtones of the OH stretching vibrations. It is also apparent from this region that Fe(2+) substitutes for Mg(2+). The intensity of bands at 7750 and 5200cm(-1) increases as the cation ratio increases in the NIR spectrum. Hydrotalcites with a magnesium amount 3 and 4 t

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Author

Ray L. Frost; Henry J. Spratt; Sara J. Palmer

Publisher

Elsevier Science; Elsevier ; Elsevier Ltd.; Pergamon Press Ltd.; Elsevier BV (ISSN 1386-1425)

Published

2009

Language

EN

Field

Chemistry (Physical Sciences)