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On the Synthesis of Optically Pure Monofluorocyclohexanol Derivatives by the Fluorinated Sulfoxide Chiron Route by Alberto Arnone; Pierfrancesco Bravo; Massimo Frigerio; Fiorenza Viani; Giancarlo Cavicchio; Marcello Crucianelli is a Chemistry article available to read on EtoBox.
What is On the Synthesis of Optically Pure Monofluorocyclohexanol Derivatives by the Fluorinated Sulfoxide Chiron Route about?
## AbM MonofluoroqzYohexonols 1 ore obtoined in opticoily pure $orm through rodicol cyclizotion of gemchlorafluoroheptenols 2 which derive@m the condensation of a-lithium d&votive of sul$oxtde 3 on rocemic ethyl chlorojluoroocetate 4, and hya?ide-promoted reduction of the intermediote ketones 5. Some considerations on the stereochemical course of the radical promoted cyclizotion reaction follow.
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- Author
- Alberto Arnone; Pierfrancesco Bravo; Massimo Frigerio; Fiorenza Viani; Giancarlo Cavicchio; Marcello Crucianelli
- Publisher
- Elsevier Science; Elsevier ; Elsevier Ltd.; Elsevier BV (ISSN 0040-4020)
- Published
- 1994
- Language
- EN
- Field
- Chemistry (Physical Sciences)