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Can I read Thermal decomposition of some perfluoroalkyl grignard reagents. Synthesis of trans-1-halo and trans-1-alkylperfluorovinyl compounds on EtoBox?
Thermal decomposition of some perfluoroalkyl grignard reagents. Synthesis of trans-1-halo and trans-1-alkylperfluorovinyl compounds by R.D. Howells; H. Gilman is a Chemistry article available to read on EtoBox.
What is Thermal decomposition of some perfluoroalkyl grignard reagents. Synthesis of trans-1-halo and trans-1-alkylperfluorovinyl compounds about?
The thermal decomposition of perfluoroalkyl Grignard reagents (RfMgX), formed from halogen-metal exchange with alkyl Grignard reagents, provides a good synthetic route to trans-l-haloperfluorovinyl compounds. The decomposition of R,MgX (where X = Cl, Br, I) in the presence of RMgX generally leads to a mixture of truns-l-alkylperfluorovinyl and transl-haloperfluorovinyl compounds. However, the choice of RMgX with respect to both the alkyl group and halogen is critical as regards the formation of the truns-1-alkylperfluorovinyl compounds. Several possible mechanisms are suggested to account for the experimental observations. TABLE 3 (continued) Trans.R&!F%FX compound Chemical shiftsb (ppm) Coupling constants (Hz) X = CH,CH, w,\* -117.4 J(F,, Fb) = 133 F, -139.
Who reads Thermal decomposition of some perfluoroalkyl grignard reagents. Synthesis of trans-1-halo and trans-1-alkylperfluorovinyl compounds?
It is typically read by researchers, students, and practitioners in Chemistry.
- Author
- R.D. Howells; H. Gilman
- Publisher
- Elsevier Science; Elsevier ; Elsevier BV (ISSN 0022-1139)
- Published
- 1975
- Language
- EN
- Field
- Chemistry (Physical Sciences)